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Core Unit #1 – Foundation of DAT Organic Chemistry Tutorial 01: Introduction to DAT Organic Chemistry Dental Admissions Test Computer based test format of the DAT The DAT Natural Sciences focus areas DAT Organic Chemistry comprehension areas Test-preparation strategies Test-taking strategies How to attack and solve Organic Chemistry problems Organic Chemistry I Review: Highlights of Key Reactions, Mechanisms, and Principles 1 Some Arrow-Pushing Guidelines (Section 1.14) 1. Arrows follow electron movement. 2. Some rules for the appearance of arrows • The arrow must begin from the electron source. There are two sources: a. An atom (which must have a lone pair to give) b. Master Organic Chemistry Study Guides See more. Organic Chemistry Summary Sheet on Alkane Nomenclature Mortgage With Points Key: 4995050813 Org 1 Summary Sheets See more. Master Organic Chemistry Study Guides. The 20-Page Summary Of Org 1 That Should Have Come With Your Textbook. to check out more great organic chemistry “cheat sheets” ! 1 2 3 Br Substitution occurs with a mixture of retention and inversion at a stereocenter H 2O 1 2 HO 1 2 3 OH retention inversion + H 3O Br The rate of the reaction is ONLY sensitive to the concentration of the substrate (and not the nucleophile) Rate [12 3 4 Br] 2 3 4 H 2O ] 1 2 3 Quick Index Quick Index Organic Chemistry Reagent Guide Organic Chemistry Reagent Guide AgNO 3 Silver nitrate SN1 reactions AIBN Initiator for free radical reactions AlBr 3 Aluminum bromideCatalyst for additions to aromatic rings BH 3 Borane Hydroboration Br 2 Bromine Adds to alkenes, aromatic rings BsCl Benzenesulfonyl chloride Part I Library of Synthetic Reactions 1 Note that this is a partial list of reactions 1 Graphics are obtained mostly from Stony Brook University CHE 327 PowerPoint slides and Organic Chemistry , 10th Edition by Solomons and ryhle.F 3 a free radical process. m-CPBA Reductive workup: Zinc (Zn), or dimethyl sulfide (DMS, Me 2S) is a reducing agent. It reduces excess ozone, allowing for isolation of the aldehyde. H 2O 2 "Master Organic Chemistry" masterorganicchemistry.com Oxidative workup: Hydrogen peroxide is used to obtain the carboxylic acid instead of aldehyde. + + Br R RR

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